Michele Kearney's Nuclear Wire

Major Energy and Environmental News and Commentary affecting the Nuclear Industry.
Showing posts with label Nuclear reprocessing. Show all posts
Showing posts with label Nuclear reprocessing. Show all posts

Friday, January 7, 2011

India opens new reprocessing plant

India opens new reprocessing plant
Nuclear scientists and engineers were called 'nation builders' by prime minister Manmohan Singh as he inaugurated India's latest reprocessing plant.

Manmohan Singh at Tarapur
Singh opens the Power Reactor Fuel
Reprocessing Plant-2
The facility at Tarapur will break down highly radioactive used nuclear fuel to extract uranium and plutonium for reuse in fast neutron reactors.
"We have come a long way since the first reprocessing of spent fuel in India in 1964 at Trombay," said Singh at yesterday's ceremony, "The recycling and optimal utilization of uranium is essential to meet our current and future energy security needs."



There are already several reprocessing plants in India - all operated by the Bhabha Atomic Research Centre - at Tarapur, Trombay and Kalpakkam. Small plants at each site were supplemented in 1998 by a new one of 100 tonnes per year at Kalpakkam, and this is now being extended to so that it may handle carbide fuel from the Fast Breeder Test Reactor.

The new plant inaugurated yesterday at Tarapur also has a capacity of 100 tonnes per year, and another entirely new facility is under construction at Kalpakkam.

Experts at the International Atomic Energy Agency told World Nuclear News that this second reprocessing plant at Tarapur is not among the facilities covered by the early 'type 66' safeguards agreement or the more comprehensive India-specific safeguards regime agreed last year.

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Thursday, December 30, 2010

Fueling America’s nuclear renaissance by reprocessing nuclear fuel By Dr. Bernard L. Weinstein

Fueling America’s nuclear renaissance by reprocessing nuclear fuel

By Dr. Bernard L. Weinstein - 12/21/10 11:43 AM ET

Earlier this year, President Barack Obama did an about-face and started voicing support for a revival of America’s nuclear power industry. To that end, he proposed a sizeable increase in federal loan guarantees to stimulate the construction of new commercial reactors. Then a few weeks ago, Department of Energy (DOE) Secretary Steven Chu stated that Congress should include nuclear power as part of any renewable energy mandates.
But at the same time, the president continues to insist that Yucca Mountain in Nevada — the intended repository for spent nuclear fuel — be abandoned as a disposal site even before it opens. Should this happen, some 60,000 metric tons of spent fuel will remain in temporary on-site storage at 65 plants, and the power industry’s interest in building new nuclear plants could quickly evaporate.
Since 1982, utilities have paid almost $17 billion into the Nuclear Waste Fund, an account administered by the DOE that continues to grow by $800 million annually, to cover the costs of permanent disposal. Even after spending $10 billion at Yucca Mountain, with accumulated interest the fund balance is currently around $20 billion. Not surprisingly, 16 utilities, along with the National Association of Regulatory Utility Commissioners, have sued the DOE to halt further collection of fees, arguing that the country no longer has a disposal plan after ruling out Yucca Mountain.
The Obama administration now says it supports the temporary storage of spent fuel at power plants while technology paves the way for an alternative solution. In fact, that technology already exists — nuclear fuel reprocessing. Given the uncertainty over the future of Yucca Mountain, and the potential explosion of litigation that will only increase taxpayer exposure, why not rethink the decades-old ban on this technology? The ban was first imposed by President Jimmy Carter in the mid-1970s on the grounds it could lead to the proliferation of nuclear weapons. But that hasn’t stopped France, Britain, Russia, China and South Korea from pursuing fuel reprocessing; and no plutonium has ever been diverted from recycling facilities for weapons production in these countries.
With reprocessing, a technology that was developed in the United States, valuable plutonium and uranium in spent fuel are removed and then chemically processed into a mixed-oxide fuel that can be used again in a reactor to generate additional electricity. Up to 95 percent of the spent fuel volume can be reprocessed, leaving only about 5 percent to decay in a few centuries. Importantly, reducing the volume of spent fuel through reprocessing would simplify the challenge of storage and disposal. What’s more, squeezing more energy out of spent fuel would be beneficial both to the nation’s economy and the environment. By using reprocessed fuel, we generate more electricity for American homes and businesses while at the same time reducing greenhouse gas emissions.
One reprocessing facility is already being constructed in South Carolina to recycle surplus plutonium from nuclear weapons into a mixed-oxide fuel for use in nuclear power plants. Some of the funds that have accumulated in the Nuclear Waste Fund could be used to build a similar plant for recycling used fuel from commercial nuclear facilities.
About a year ago the DOE appointed a blue ribbon commission to evaluate policy options for a safe, long-term solution to nuclear waste disposal. The 15-member Commission on America’s Nuclear Future, co-chaired by former Congressman Lee Hamilton of Indiana and former National Security Advisor Brent Scowcroft, and including scientists, industry representatives, and heads of environmental research organizations, will issue its final report by January 2012.
Recycling of spent nuclear fuel should be at the top of the Commission’s agenda. Reprocessing, along with centralized interim storage, makes a lot more sense than banking used fuel at nuclear plants indefinitely. At the same time, we should be doing everything we reasonably can to advance America’s nuclear renaissance, a task made more difficult by the ongoing uncertainty regarding the final disposition of spent fuel.
Dr. Weinstein is associate director of the Maguire Energy Institute in the Cox School of Business at Southern Methodist University in Dallas. Between 1985 and 1995, he was with the speakers’ bureau of the Nuclear Energy Institute. His email address is bweinstein@smu.edu
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Monday, September 20, 2010

Processing of Used Nuclear Fuel

Processing of Used Nuclear Fuel

(Updated September 2010) 
  • Used nuclear fuel has long been reprocessed to extract fissile materials for recycling and to reduce the volume of high-level wastes. 
  • New reprocessing technologies are being developed to be deployed in conjunction with fast neutron reactors which will burn all long-lived actinides. 
  • A significant amount of plutonium recovered from used fuel is currently recycled into MOX fuel; a small amount of recovered uranium is recycled. 
A key, nearly unique, characteristic of nuclear energy is that used fuel may be reprocessed to recover fissile and fertile materials in order to provide fresh fuel for existing and future nuclear power plants. Several European countries, Russia and Japan have had a policy to reprocess used nuclear fuel, although government policies in many other countries have not yet addressed the various aspects of reprocessing.
Over the last 50 years the principal reason for reprocessing used fuel has been to recover unused uranium and plutonium in the used fuel elements and thereby close the fuel cycle, gaining some 25% more energy from the original uranium in the process and thus contributing to energy security. A secondary reason is to reduce the volume of material to be disposed of as high-level waste to about one fifth. In addition, the level of radioactivity in the waste from reprocessing is much smaller and after about 100 years falls much more rapidly than in used fuel itself.
In the last decade interest has grown in recovering all long-lived actinides together (i.e. with plutonium) so as to recycle them in fast reactors so that they end up as short-lived fission products. This policy is driven by two factors: reducing the long-term radioactivity in high-level wastes, and reducing the possibility of plutonium being diverted from civil use – thereby increasing proliferation resistance of the fuel cycle. If used fuel is not reprocessed, then in a century or two the built-in radiological protection will have diminished, allowing the plutonium to be recovered for illicit use (though it is unsuitable for weapons due to the non-fissile isotopes present).
Reprocessing used fuela to recover uranium (as reprocessed uranium, or RepU) and plutonium (Pu) avoids the wastage of a valuable resource. Most of it – about 96% – is uranium, of which less than 1% is the fissile U-235 (often 0.4-0.8%); and up to 1% is plutonium. Both can be recycled as fresh fuel, saving up to 30% of the natural uranium otherwise required. The materials potentially available for recycling (but locked up in stored used fuel) could conceivably run the US reactor fleet of about 100 GWe for almost 30 years with no new uranium input.
So far, almost 90,000 tonnes (of 290,000 t discharged) of used fuel from commercial power reactors has been reprocessed. Annual reprocessing capacity is now some 4000 tonnes per year for normal oxide fuels, but not all of it is operational.
Between now and 2030 some 400,000 tonnes of used fuel is expected to be generated worldwide, including 60,000 t in North America and 69,000 t in Europe.
World commercial reprocessing capacity1,2 
(tonnes per year)
LWR fuel France, La Hague
1700
UK, Sellafield (THORP)
900
Russia, Ozersk (Mayak)
400
Japan (Rokkasho)
800
Total (approx)
3800
Other nuclear fuels UK, Sellafield (Magnox)
1500
India
275
Total (approx)
1750
Total civil capacity
5550
Products of reprocessing
The composition of reprocessed uranium (RepU) depends on the initial enrichment and the time the fuel has been in the reactor, but it is mostly U-238. It will normally have less than 1% U-235 (typically about 0.5% U-235) and also smaller amounts of U-232 and U-236 created in the reactor. The U-232, though only in trace amounts, has daughter nuclides which are strong gamma-emitters, making the material difficult to handle. However, once in the reactor, U-232 is no problem (it captures a neutron and becomes fissile U-233). It is largely formed through alpha decay of Pu-236, and the concentration of it peaks after about 10 years of storage.
The U-236 isotope is a neutron absorber present in much larger amounts, typically 0.4% to 0.6% – more with higher burn-up – which means that if reprocessed uranium is used for fresh fuel in a conventional reactor it must be enriched significantly more (e.g. up to one-tenth more) than is required for natural uraniumb. Thus RepU from low burn-up fuel is more likely to be suitable for re-enrichment, while that from high burn-up fuel is best used for blending or MOX fuel fabrication.
The other minor uranium isotopes are U-233 (fissile), U-234 (from original ore, enriched with U-235, fertile), and U-237 (short half-life beta emitter). None of these affects the use of handling of the reprocessed uranium significantly. In the future, laser enrichment techniques may be able to remove these isotopes.
Reprocessed uranium (especially from earlier military reprocessing) may also be contaminated with traces of fission products and transuranics. This will affect its suitability for recycling either as blend material or via enrichment. Over 2002-06 USEC successfully cleaned up 7400 tonnes of technetium-contaminated uranium from the US Department of Energy.
Most of the separated uranium (RepU) remains in storage, though its conversion and re-enrichment (in UK, Russia and Netherlands) has been demonstrated, along with its re-use in fresh fuel. Some 16,000 tonnes of RepU from Magnox reactors in UK has been usedc to make about 1650 tonnes of enriched AGR fuel. In Belgium, France, Germany and Switzerland over 8000 tonnes of RepU has been recycled into nuclear power plants. In Japan the figure is over 335 tonnes in tests and in India about 250 t of RepU has been recycled into PHWRs. Allowing for impurities affecting both its treatment and use, RepU value has been assessed as about half that of natural uranium.
Plutonium from reprocessing will have an isotopic concentration determined by the fuel burn-up level. The higher the burn-up levels, the less value is the plutonium, due to increasing proportion of non-fissile isotopes and minor actinides, and depletion of fissile plutonium isotopesd. Whether this plutonium is separated on its own or with other actinides is a major policy issue relevant to reprocessing (see section on Reprocessing policies below).
Most of the separated plutonium is used almost immediately in mixed oxide (MOX) fuel. World MOX production capacity is currently around 200 tonnes per year, nearly all of which is in France (see page on Mixed Oxide (MOX) Fuel).
Inventory of separated recyclable materials worldwide3 
Quantity (tonnes) Natural U equivalent (tonnes)
Plutonium from reprocessed fuel 320 60,000
Uranium from reprocessed fuel 45,000 50,000
Ex-military plutonium 70 15,000
Ex-military high-enriched uranium 230 70,000
More at link
http://www.world-nuclear.org/info/inf69.html

 

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Saturday, September 18, 2010

All Things Nuclear Insights on Science and Security Fact, Fiction and Faith: The Endless Debate Over Reprocessing | by Ed Lyman


My testimony before the Reactor and Fuel Cycle Technology Subcommittee of the Blue Ribbon Commission on America’s Nuclear Future (the “BRC”) elicited a predictable and depressing reaction from certain corners of the blogosphere. I informed the Subcommittee that although UCS does not oppose nuclear energy per se, we do oppose reprocessing spent nuclear fuel because of the security, safety and proliferation risks that it poses. I then presented the Subcommittee with a summary of the rationale behind our position, complete with numerous technical references. The UCS position was in direct opposition to that of four of the six members of the panel I was on (representing AREVA, General Electric-Hitachi, Westinghouse and Energy Solutions), who all supported spent fuel reprocessing and “recycling” strategies of one sort or another.
My testimony appears to have given certain bloggers heartburn. Rod Adams of Atomic Insights saw fit to criticize my competence, my understanding of technology and my use of what he called “unsubstantiated statements and vague references.” Yet he was unable to actually point to anything specific in my testimony that he could contradict. Instead, he posted a video clip of my presentation and invited his loyal readers to defend the faith by “dissecting” my testimony.
I would be more than happy to engage Mr. Adams’ readers in a technical debate on these issues, so I thought, frankly, that this was a fine idea. However, two weeks later, it appears that Mr. Adams’ gambit has backfired. Out of twenty comments, only one actually professes any knowledge of any of the references that I cited. Most simply repeat unsubstantiated assertions themselves. Some claim that I must have misinterpreted the references but did not actually bother to look them up. Several are ad hominem attacks on me or UCS. A couple actually agree with some of the points I made. All in all, not a very impressive showing. In fact, I found only two statements that merit a response. Below, I respond to those statements.
Mr. Adams and his readers should rest assured that every statement I make is supported by direct references and transparent analysis. In the future, I’d appreciate that observers interested in a technical debate actually consult my written works and references before throwing darts.
There are three main points to my testimony.
1. Reprocessing spent nuclear fuel has only a marginal impact on the volume of high-level waste requiring disposal in a geologic repository, while significantly increasing the volume of other forms of nuclear waste also requiring secure disposal.

Some reprocessing advocates argue that the technology can reduce the volume of high-level nuclear waste requiring disposal in a geologic repository. On the Atomic Insights blog, Lars Jorgensen says that it is “easy” for any recycling system to significantly reduce waste volume.

However, reprocessing actually increases, not decreases, the total volume of long-lived nuclear waste that must be stored and eventually buried in a geologic repository  It only slightly reduces the volume of high-level nuclear waste that must be disposed of in a repository, as required by the Nuclear Waste Policy Act. At the same time, it significantly increases the volume of “greater-than-class-C” low-level waste, which cannot be legally disposed of in near-surface low-level waste facilities and would therefore need to be buried in a geologic repository as well. In addition, reprocessing increases the volume of low-level waste that must be disposed of in NRC-licensed near-surface facilities. Only one new low-level waste facility has been licensed in the United States in decades, and no policy (not to mention a repository) exists for disposal of GTCC LLW.
According to Argonne National Laboratory data cited by the Energy Department’s 2008 Global Nuclear Energy Draft Programmatic Environmental Impact Statement, compared to the once-through cycle, a fast-reactor-based reprocessing and recycle system would increase the total volume of radioactive waste by a factor of about seven. In particular, reprocessing would generate, in terms of volume,
  • Seven times as much Class A, B and C low-level waste (LLW)
  • 166 times as much greater-than-class-C LLW (over 8,000 cubic meters annually on average)
  • only 25% less high-level waste (HLW)
The last data point conflicts with public statements being made by AREVA, which continues to claim that “recycling reduces by 75% the volume of high-level waste that must be sent to a repository.” However, this assertion is not even supported by AREVA’s own data. According to a 2009 presentation to the Nuclear Waste Technical Review Board, Dorothy Davidson of AREVA indicated that the volume of reprocessing waste requiring geologic disposal (vitrified high-level waste and compacted hulls and end pieces) was 10 cubic feet per metric ton heavy metal of initial spent fuel reprocessed (10 ft3/MTHM). In the same presentation, Davidson claimed that this should be compared a spent fuel volume of 45 ft3/MTHM, so that reprocessing results in a more than four-fold decrease in waste volume.

However, this latter figure is incorrect. As Table S.3-1 shows, the volume of light-water reactor spent fuel is actually closer to 15.8 ft3/MTHM (0.45 m3/MTHM). Therefore, the HLW volume per MTHM according to AREVA’s own data is only about 37% less than the initial volume of spent fuel – a much less impressive reduction than the 75% cited by AREVA, and one much closer to the Argonne/DOE estimate. Apparently, this discrepancy stems from the fact that AREVA did not directly compare the volume of HLW to the volume of spent fuel, but compared the volume of HLW to the volume of the spent fuel waste disposal package that was originally considered for the Yucca Mountain repository, which had a significant amount of empty space. This is not an apples-to-apples comparison.

But in any event, heat load, not volume, is typically the limiting factor in a geologic repository. If plutonium and other transuranic elements such as americium are removed with very high separation factors, the heat load of the residual waste will be reduced. However, unless the actinides that are removed from the spent fuel are actually destroyed through fission in a reasonable period of time, they will have to be stored for an indefinite period (posing many of the same concerns as indefinite interim storage of spent fuel), and eventually will have to be disposed of in a repository. Yet as the discussion in the next section indicates, reprocessing and transuranic recycle systems are not capable of significantly reducing total actinide inventories in a reasonable period of time. 

2. Reprocessing and recycling spent nuclear fuel, whether in thermal or fast reactors, cannot effectively reduce the total quantity of hazardous radionuclides like plutonium and other transuranic elements that would require disposal in a repository.

Numerous studies have shown that fast reactor (FR) recycle systems are very slow and inefficient in actually fissioning transuranic elements, even if they operate in burner mode with very low conversion ratios. A recent study by the Electric Power Research Institute (EPRI) and Electricité de France (EdF) examined the impact of phasing in a fast reactor system operating in tandem with light-water reactors (LWRs) (35 percent FRs and 65 percent LWRs) and operating at a conversion ratio of 0.5, while keeping constant the total U.S. nuclear generating capacity. [1] The study found that the total inventory of plutonium and other transuranics would increase to over 1500 metric tons - roughly three times today’s inventory - and would remain essentially constant after that. Thus the system is simply not capable of reducing the total transuranic inventory, and the popular image that such a system can “burn up” nuclear waste is simply not accurate.

The EPRI study also compares the transuranic inventory in the system to the inventory that would accumulate in spent fuel if the U.S. continued with the once-through cycle. The analysis finds that the system would have to operate for 70 years just to reduce the total inventory of transuranics in the system by 50 percent relative to the once-through inventory. To reduce the inventory by 90 percent would require continuous operation for 632 years. Thus the system of reprocessing plants, fuel fabrication plants, fast reactors and associated facilities would have to operate over a period spanning many generations – and be rebuilt many times – before it could achieve a significant reduction in actinide inventory and a significant decrease in repository heat load compared to the once-through cycle. The paper concludes that “the analysis for the specific [recycling] scenario considered shows that it would take many decades, even centuries, for significant waste management benefits to materialize.” This is consistent with the one of the conclusions of the MIT study “The Future of the Nuclear Fuel Cycle,” released earlier this week – namely, that the choice of fuel cycle would make “little difference” in the total transuranic inventory in this century.

Proposals that require the essentially indefinite reprocessing and recycling of spent fuel do not provide a suitable foundation of nuclear waste management because they are inconsistent with the “intergenerational equity” principle. This principle, which underlies the rationale for a geologic repository for nuclear waste, includes the provisions that (1) those who generate the wastes should take responsibility, and provide the resources, for the management of these materials in a way which will not impose undue burdens on future generations; and (2) that a waste management strategy should not be based on a presumption of a stable societal structure for the indefinite future, nor of technological advance; rather it should aim at bequeathing a passively safe situation which places no reliance on active institutional controls.

A system that would require hundreds of years of costly and complex operations to achieve only a modest reduction in repository space requirements is not consistent with these principles. Some reprocessing advocates argue that nuclear materials that are in the fuel cycle – that is, in reactors, fuel fabrication plants, and above-ground storage facilities – need not be counted as wastes. This is only true, however, as long as the system is running. If it shuts down for any reason, these materials will require secure disposal. Thus our generation would be bequeathing to future generations the obligation of keeping the system going, without regard to cost or risk. This is clearly inconsistent with intergenerational equity.
3. Advanced reprocessing technologies do not significantly reduce nuclear proliferation and nuclear terrorism risks relative to current reprocessing technologies that produce separated plutonium.

Energy Secretary Chu has spoken of the proliferation risks associated with conventional reprocessing technology, as practiced in France and Japan, and has expressed confidence that the U.S. can develop alternatives that are “proliferation-resistant.” One of the goals of the Bush Administration’s Global Nuclear Energy Partnership program (GNEP) was also to develop so-called proliferation-resistant reprocessing technologies that did not produce “separated” plutonium.

However, a study conducted by the nuclear weapons labs reviewed the entire suite of technologies that were under study, including modified aqueous reprocessing and pyrometallurgical processing (“pyroprocessing”), with regard to their potential for reducing proliferation concerns. [2] The study found that the products of these processes, mixtures of plutonium and other actinides such as neptunium, americium and curium, are attractive for use in nuclear weapons or nuclear explosive devices. It concluded that there is no “silver bullet” technology that would eliminate the safeguards and security issues associated with reprocessing, and also that “none of the proposed flowsheets examined to date justify reducing international safeguards or physical security protection levels. All of the reprocessing or recycling technologies evaluated to date still need rigorous safeguards and high levels of physical protection.”

It should be noted that this study only analyzed the direct usability of these materials in nuclear weapons without further processing. It did not consider the potential for theft and off-site purification of these materials. As we and our colleagues have noted at length elsewhere, alternative reprocessing technologies under consideration do not confer significant self-protection against theft.

If stolen, these materials could be readily processed to produce even more attractive materials for weapons use.

One of the Atomic Insights blog post replies (Steve Darden, September 3), claimed that I misrepresented Bathke’s study. Darden asserted that the statements I made regarding the study’s conclusions with regard to subnational groups (terrorists) actually applied only to state-level actors. However, Darden is wrong. If he had actually read any of Bathke’s reports, he would have learned that the so-called Figure of Merit (FOM1) that I used “is applicable for evaluating the attractiveness of SNM or ANM for a sub-national group, for most of the less advanced proliferant nations, or for a technically advanced proliferant state.”
The other Figure of Merit (FOM2), which Mr. Darden asserts is designed for a “sub-state level actor,” is actually intended only “for a very few relatively unadvanced proliferant nations that desire a reliably high yield.” Thus Mr. Darden is wrong in attacking me for “abusing such metrics.”
Notes:
[1] A. Machiels, S. Massara and C. Garzenne, “Dynamic Analysis of a Deployment Scenario of Fast Burner Reactors in the U.S. Nuclear Fleet,” Proceedings of the Global 2009 Conference, Paris, France, September 8-11, 2009, pp. 2567-2574. Also cited in the testimony of J. Kessler, EPRI, to the July meeting of the Reactor and Fuel Cycle Technology Subcomittee of the Blue-Ribbon Commission.
[2] C. Bathke et al., “An Assessment of the Attractiveness of Material Associated with a MOX Fuel Cycle From as Safeguards Perspective,” 50th Annual Meeting of the Institute of Nuclear Materials Management, Tucson, AZ, July 2009.
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Tuesday, August 31, 2010

Nuclear fuel reprocessing needs support, not subsidies: Areva exec

Loan guarantees are key to nuclear reprocessing, exec says
 

The push for advanced technology to reprocess used nuclear fuel needs a decisive U.S. policy that includes loan guarantees, said Alan Henson, Areva executive vice president of technologies and used-fuel management. His statement came in response to Marvin Resnikoff, senior associate of Radioactive Waste Management Associates, who told a subcommittee of the federal commission on nuclear waste that no company would develop reprocessing facilities unless it received federal supports. Platts
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